Archive for June 13th, 2008

How do element “lamps” allow us to observe multiple electron transitions?

Friday, June 13th, 2008
caulfield789 asked:


The way that chemistry students are usually introduced to the concept of atomic spectra is through a discussion of element “lamps” - like the helium lamp or the hydrogen lamp. (Consider, for example, the images at http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/atspect.html.) I do not understand why splitting the light emitted from these lamps (by using, say, a prism) allows us to see a myriad of colors as opposed to just one color. How do these element lamps energize the electrons in such a way that we see wavelengths of light corresponding to multiple electron transitions instead of just one? (When one conducts a flame test for metallic ions, for example, one sees only a single color, not multiple ones…unless I’ve got it all wrong.)

Christian
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